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Reactions of Amines with Copper(II) Ions

Edexcel A-level ChemistryAmines, Amides, Amino Acids and ProteinsLesson 6 of 12

Amines react with aqueous copper(II) ions in two different ways, depending on how much amine is added. The reaction closely mirrors that of ammonia.

Copper(II) sulfate solution contains the pale blue complex ion [Cu(H2O)6]2+.

A few drops of amine. An aqueous amine such as butylamine is basic. It removes protons from two water ligands, and a pale blue precipitate of copper(II) hydroxide forms:

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Key terms in this lesson

coordinate bond
A covalent bond in which both shared electrons come from the same atom.

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