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Basicity of Amines

Edexcel A-level ChemistryAmines, Amides, Amino Acids and ProteinsLesson 2 of 12

Amines are Brønsted-Lowry bases: the lone pair on the nitrogen atom can accept a proton (H+). In water, an amine removes a proton from a water molecule, so the solution contains excess hydroxide ions and is alkaline:

CH3CH2NH2 + H2O ⇌ CH3CH2NH3+ + OH−

Like ammonia, amines are weak bases, so the equilibrium lies to the left. How strong a base is depends on how available the nitrogen lone pair is to accept a proton.

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