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Qualitative Tests for Phenols

OCR A-level Organic ChemistryChromatography and Qualitative AnalysisLesson 8 of 10

Phenols have an −OH group bonded directly to a benzene ring. Two properties are used to identify them.

1. Phenol is a weak acid. It is more acidic than an alcohol but less acidic than a carboxylic acid.

• Phenol reacts with a strong base, sodium hydroxide, to form a salt and water:

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Key terms in this lesson

electrophilic substitution
A reaction mechanism in which an electrophile is attracted to and attacks a region of high electron density, such as the delocalised ring in benzene, displacing a hydrogen atom.

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