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Qualitative Tests for Alkenes

OCR A-level Organic ChemistryChromatography and Qualitative AnalysisLesson 6 of 10

Alkenes contain a carbon−carbon double bond, C=C. The test for this unsaturation is bromine water.

Add a few drops of bromine water to the sample and shake.

• Positive result: the orange bromine water decolourises (turns colourless).
• Negative result: the bromine water stays orange, e.g. with an alkane.

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Key terms in this lesson

electrophilic addition
A reaction mechanism in which an electrophile is attracted to and attacks an electron-rich double bond, and a nucleophile then bonds to the resulting carbocation.

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