Gas Chromatography
Gas chromatography (GC) separates volatile components of a mixture, and is sensitive enough to detect very small amounts.
• The mobile phase is an unreactive carrier gas, such as helium or nitrogen.
• The stationary phase is a high-boiling liquid coated on an inert solid support (or on the inside wall) inside a long, thin, coiled capillary column.
• The column is kept inside an oven so the sample stays as a gas.
A small sample is injected, vaporises and is carried through the column by the carrier gas. Components separate by their relative solubility in the liquid stationary phase: a component that is more soluble in the liquid spends longer dissolved in it and moves through the column more slowly.
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Key terms in this lesson
- stationary phase
- The phase in chromatography that does not move, and interacts with the components of a mixture to different extents.
- mobile phase
- The phase in chromatography, a liquid solvent or gas, that moves through or over the stationary phase carrying the mixture's components.
More in Chromatography and Qualitative Analysis
- Chromatography
- Thin-Layer Chromatography
- Rf Values
- Retention Times and Peak Areas
- Qualitative Tests for Alkenes
- Qualitative Tests for Haloalkanes
- Qualitative Tests for Phenols
- Qualitative Tests for Carbonyls
All 10 lessons in Chromatography and Qualitative Analysis · All OCR A-level Organic Chemistry topics