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Qualitative Tests for Carboxylic Acids

OCR A-level Organic ChemistryChromatography and Qualitative AnalysisLesson 10 of 10

Carboxylic acids are identified by their acidity. They are weak acids, but strong enough to react with carbonates and release carbon dioxide.

Method: add aqueous sodium carbonate (or sodium hydrogencarbonate, or solid carbonate) to the sample.

• Positive result: effervescence (fizzing).
• Bubble the gas through limewater: it turns milky (cloudy), confirming CO2.

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