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Electron Pair Repulsion Theory

OCR AS-level ChemistryShapes and Intermolecular ForcesLesson 1 of 13

The electron pair repulsion theory can be used to predict the shape and bond angles of covalent molecules and polyatomic ions.

Electron pairs repel each other so they are arranged as far apart as possible. This minimises repulsion and holds the molecule in a particular shape.

The shape of a molecule depends on the number of electron pairs.

Diagram

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Key terms in this lesson

Ion
A positively or negatively charged atom or group of atoms, formed by the loss or gain of electrons.
Polyatomic ion
An ion that is made up of more than one element.
Lone pair
A pair of outer-shell electrons that is not involved in bonding.

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