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Electron Pair Repulsion Theory

The electron pair repulsion theory can be used to predict the shape and bond angles of covalent molecules and polyatomic ions.
Electron pairs repel each other so they are arranged as far apart as possible. This minimises repulsion and holds the molecule in a particular shape.

The shape of a molecule depends on the number of electron pairs.
A lone pair of electrons is slightly closer to the central atom and therefore takes up more space than a bonded pair of electrons. As a result, repulsion from a lone pair is stronger than from a bonding pair. For each lone pair, the bond angle decreases by about 2.5°Double and triple bonds are treated as a single bonding region.

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Specification: OCR Chemistry A (H032), AS-level, 2.2.2 Bonding and structure. Topic: Shapes and Intermolecular Forces.

Key terms in this lesson

Ion
A positively or negatively charged atom or group of atoms, formed by the loss or gain of electrons.
Polyatomic ion
An ion that is made up of more than one element.
Lone pair
A pair of outer-shell electrons that is not involved in bonding.

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