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Electronegativity

Electronegativity is the attraction of a bonded atom for the pair of electrons in a covalent bond.

One of the bonded atoms may have a greater attraction for the shared pair of electrons than the other. The result is that the shared pair of electrons is not shared evenly and the electron cloud is distorted the bond becomes polar.
If the electronegativity difference is large enough (greater than 1.8) the more electronegative atom gains control of the electrons and the bond will become ionic rather than covalent.Electronegativity is measured on the Pauling scale.
Electronegativity increases across a period and up a group. Across a period, nuclear charge increases and atomic radius decreases. Up a group, atomic radius and shielding decrease. In both cases the nuclear attraction for the bonded pair of electrons increases.
HCl is a polar covalent molecule as there is a difference in the electronegativities of hydrogen and chlorine.

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Specification: OCR Chemistry A (H032), AS-level, 2.2.2 Bonding and structure. Topic: Shapes and Intermolecular Forces.

Key terms in this lesson

Covalent bond
A strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.
Atomic radius
A measure of the size of an atom, found by measuring the distance between two adjacent nuclei and dividing by two.

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