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Filling of Orbitals and Electron Pairing

OCR AS-level ChemistryElectrons and BondingLesson 2 of 7

Orbitals fill in order of increasing energy.
The order of filling is:
1s 2s 2p 3s 3p 4s 3d 4p 5s 4d 5p
The 4s orbital is filled before the 3d orbital as the 3d orbital has a higher energy than the 4s orbital.

Each orbital can hold up to 2 electrons as long as they have opposite spins.

The opposite spin helps to counteract the repulsion between electrons in the same orbital. Orbitals with the same energy are occupied singly and then paired when there is no unoccupied orbital left.

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Key terms in this lesson

Atomic number
The number of protons in the nucleus of an atom.
Atomic orbital
A region in space where there is a high probability (90-95%) of finding an electron.
Electron configuration
The notation showing the arrangement of an atom's electrons in shells and sub-shells, such as 1s2 2s2 2p6.

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