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Covalent Bonding

A covalent bond is a localised bond formed as a strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

Covalent bonds only form between atoms of non-metallic elements.

Non-metals can exist as molecules formed from covalently bonded atoms or in the case of carbon and silicon giant covalent lattices.
Non-metal elements can combine to form covalent compounds.In a covalent bond, atomic s, p, d and f orbitals overlap to form molecular orbitals. Each atomic orbital contains a single electron.
The molecular orbital contains the shared pair of electrons. The shared electrons are attracted to the nuclei of each atom and this holds the two atoms together.The bonded atoms usually have the same electron configuration as the noble gas at the end of the same period (but not always, for example in BF3 or PCl5).
The average bond enthalpy measures the strength of a covalent bond. The greater the bond enthalpy the stronger the covalent bond.

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Specification: OCR Chemistry A (H032), AS-level, 2.2.2 Bonding and structure. Topic: Electrons and Bonding.

Key terms in this lesson

Atomic orbital
A region in space where there is a high probability (90-95%) of finding an electron.
Electron configuration
The notation showing the arrangement of an atom's electrons in shells and sub-shells, such as 1s2 2s2 2p6.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.
Enthalpy
A measure of the total energy of a chemical system.
Average bond enthalpy
The energy required to break one mole of a specified type of bond in a gaseous molecule, averaged over many different molecules.

More in Electrons and Bonding

All 7 lessons in Electrons and Bonding · All OCR AS-level Chemistry topics