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Polyatomic Ions

Edexcel AS-level ChemistryDiscrete MoleculesLesson 10 of 25

The carbonate CO32- and nitrate ions NO3- are trigonal planar as they both have three bonding regions of electron density surrounding the central atom.

Diagram

The shape of a polyatomic ion is predicted in exactly the same way as for a molecule: count the bonding regions and lone pairs around the central atom, then apply electron pair repulsion theory. The charge on the ion must be included when counting the electrons.

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Key terms in this lesson

electron pair repulsion theory
Electron pairs around a central atom arrange themselves as far apart as possible to minimise repulsion, deciding molecular shape.
lone pair
A pair of outer shell electrons on an atom that is not involved in bonding.
oxonium ion
The ion H3O+, formed when a water molecule accepts a proton from an acid.

More in Discrete Molecules

All 25 lessons in Discrete Molecules · All Edexcel AS-level Chemistry topics