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Fractional Distillation

Edexcel AS-level ChemistryAlcoholsLesson 7 of 16

Fractional distillation separates a mixture of miscible liquids whose boiling temperatures are close together. Simple distillation cannot do this well, because the vapour from such a mixture contains a lot of both liquids.

A fractionating column is fitted between the flask and the still head. The column is packed with glass beads or rings, which give a large surface area. There is a temperature gradient up the column: it is hottest at the bottom and coolest at the top.

Diagram

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