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Covalent bonds and Small Molecules

A covalent bond is a localised bond formed as a strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

Covalent bonds usually form between atoms of non-metallic elements.

Non-metals can exist as molecules formed from covalently bonded atoms or in the case of carbon and silicon giant covalent lattices.
Non-metal elements can combine to form covalent compounds.In a covalent bond, atomic s, p, d and f orbitals overlap to form molecular orbitals. Each atomic orbital contains a single electron.
The molecular orbital contains the shared pair of electrons. The shared electrons are attracted to the nuclei of each atom and this holds the two atoms together.The bonded atoms usually have the same electron configuration as the noble gas at the end of the same period.
The average bond enthalpy measures the strength of a covalent bond. The greater the bond enthalpy the stronger the covalent bond.

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Specification: AQA Chemistry (7404), AS-level, 3.1.3.2 Nature of covalent and dative covalent bonds. Topic: Bonding.

Key terms in this lesson

Atomic orbital
A region in space around the nucleus where there is a 95% probability of finding an electron of a given energy.
Electron configuration
The arrangement of electrons in an atom's shells and sub-shells, written using numbers and letters such as 1s2 2s2.
Enthalpy
A measure of the heat energy stored in a chemical system.
Average bond enthalpy
The energy required to break one mole of a specified type of bond in a gaseous molecule, averaged over many different molecules.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

More in Bonding

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