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Co-ordinate Bonding

A dative covalent bond or a co-ordinate bond is a covalent bond in which the shared pair of electrons has been supplied by only one of the bonding atoms.

The shared pair of electrons is supplied by a lone pair on one atom.
The ammonium ion is formed when the lone pair on the nitrogen atom in NH3 is donated to a hydrogen ion H+ with an empty orbital.
Although shown with an arrow → all four bonds are equivalent and it is not possible to tell the difference.

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Specification: AQA Chemistry (7404), AS-level, 3.1.3.2 Nature of covalent and dative covalent bonds. Topic: Bonding.

Key terms in this lesson

Atomic orbital
A region in space around the nucleus where there is a 95% probability of finding an electron of a given energy.
Covalent bond
A strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.
Lone pair
A pair of outer-shell electrons that is not involved in bonding.

More in Bonding

All 30 lessons in Bonding · All AQA AS-level Chemistry topics