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Electronegativity

Electronegativity is the attraction of a bonded atom for the pair of electrons in a covalent bond.

One of the bonded atoms may have a greater attraction for the shared pair of electrons than the other. The result is that the shared pair of electrons is not shared evenly and the electron cloud is distorted the bond becomes polar.
If the electronegativity difference is large enough (greater than 1.8) the more electronegative atom gains control of the electrons and the bond will become ionic rather than covalent.Electronegativity is measured on the Pauling scale.
Electronegativity increases across a period and up a group. Across the period and up the group, nuclear charge increases and atomic radius decreases so the size of the nuclear attraction for the bonded pair of electron increases.
HCl is a polar covalent molecule as there is a difference in the electronegativities of hydrogen and chlorine.

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Specification: AQA Chemistry (7404), AS-level, 3.1.3.6 Bond polarity. Topic: Bonding.

Key terms in this lesson

Covalent bond
A strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.
Atomic radius
A measure of the size of an atom, found by measuring the distance between two adjacent nuclei and dividing by two.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

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