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Reaction with COncnetrated Sulfuric Acid

AQA AS-level ChemistryAlkenesLesson 15 of 23

Alkenes react with cold concentrated sulfuric acid by electrophilic addition. With ethene the product is ethyl hydrogensulfate:

CH2=CH2 + H2SO4 → CH3CH2OSO2OH

In H2SO4 the O–H bonds are polar, so each hydrogen atom is δ+. That hydrogen is the electrophile.

Diagram

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Key terms in this lesson

carbocation
A positively charged carbon atom formed as a reactive intermediate when a bond breaks heterolytically.

More in Alkenes

All 23 lessons in Alkenes · All AQA AS-level Chemistry topics