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pH of a Buffer Solution

OCR A-level ChemistryAcids, Bases and BuffersLesson 11 of 15

To find the pH of any solution, you need to determine the hydrogen ions concentration. Most of the acid is undissociated for the HA can be assumed to be the original (undissociated) acid concentration. Most of the anion comes from the conjugate base which dissociates completely. Very little is from the undissociated acid. So the anion concentration is assumed to be the original conjugate base concentration.

Diagram

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Key terms in this lesson

buffer solution
A solution that resists changes in pH when small amounts of acid or alkali are added.
conjugate base
The species left after an acid has donated a proton.
acid dissociation constant Ka
The equilibrium constant for the dissociation of a weak acid in aqueous solution.
pH
A measure of the hydrogen ion concentration of a solution, defined as pH = -log10[H+].

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