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Calculating the pH of a Strong Base

The strength of a base is its ability to dissociate and generate OH- ions in solution. Strong bases are alkalis. They dissociate completely to give hydroxide ions and cations. For example, sodium hydroxide is a strong base.NaOH(aq) → Na+(aq) + OH-(aq)Since pH = -log10[H+] we need to know the hydrogen ion concentration in order to find the pH. We can use the fact that Kw = [H+] [OH-] = 1.0 x 10-14 at 25°C to find the hydrogen ion concentration.For a 0.2 moldm-3 solution of NaOH, the [H+] = Kw/ [OH-] and [H+] = 1 x 10-14/ 0.2pH = -log10 (1 x 10-14/ 0.2) = 13.3

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Specification: OCR Chemistry A (H432), A-level, 5.1.3 Acids, bases and buffers. Topic: Acids, Bases and Buffers.

Key terms in this lesson

pH
A measure of the hydrogen ion concentration of a solution, defined as pH = -log10[H+].
ionic product of water Kw
The equilibrium constant for the dissociation of water, Kw = [H+][OH-], equal to 1.0 x 10^-14 mol2dm-6 at 25 degrees C.

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