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Evidence for Delocalisation - Enthalpy of Hydrogenation

AQA A-level ChemistryAromatic ChemistryLesson 4 of 11

Enthalpy changes of hydrogenation give strong numerical evidence that benzene is more stable than the Kekulé structure.

Cyclohexene has one C=C bond. Hydrogenating it to cyclohexane releases 120 kJ per mole:

C6H10 + H2 → C6H12    ΔH = −120 kJ mol−1
Diagram

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