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ATP

ATP is the immediate energy source of a cell.ATP is a short term energy store because its bonds are unstable. Cells do not store large quantities of ATP and maintain only a few seconds supply. As a result ATP is continuously synthesised.ATP is easily hydrolysed in a single reaction. The reaction has a low activation energy and releases sufficient energy.Glucose releases 2870 kJmol-1 of energy. ATP releases 30.5 kJmol-1 of energy. This is sufficient for most cellular reactions so less energy is wasted.ATP is used for metabolic processes, movement, active transport, secretion and the activation of molecules.
ATP is adenosine triphosphate. It is a nucleotide containing ribose sugar, three phosphate groups on carbon atom-5 and the nitrogen containing base adenine.
The bonds between the phosphate groups are easily hydrolysed because the hydrolysis reactions require a low activation energy. The hydrolysis yields small amounts of energy (about 30.5 kJmol-1 for the first two bonds and 14 kJmol-1 for the third hydrolysis). ATP + H2O → ADP + Pi + energy ADP + H2O → AMP + Pi + energyAMP + H2O → adenosine + Pi + energyUsually only the first group is hydrolysed. This is coupled with metabolic reactions to provide energy for the reactions.
ATP is synthesised by ATP synthase in a condensation reaction. The reaction is the reverse of the hydrolysis reactionADP + Pi + energy → ATP + H2OATP is synthesised in plant and animal cells during processes called phosphorylation.Photophosphorylation occurs during photosynthesis.Oxidative phosphorylation occurs during respiration.Substrate level phosphorylation occurs when phosphate groups from molecules are transferred to ADP.

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Specification: OCR Biology A (H020), AS-level, 2.1.3 Nucleotides and nucleic acids and 2.1.2 Biological molecules. Topic: Biological Molecules.

Key terms in this lesson

condensation reaction
A reaction that joins two molecules together with a covalent bond, releasing a water molecule.
hydrolysis
A reaction that breaks a covalent bond between two molecules by adding a water molecule.

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