In 1924 Louis de Broglie suggested that if light waves can behave as particles, then particles such as electrons should also behave as waves. He proposed that every moving particle has a wavelength, now called the de Broglie wavelength:λ = h / p = h / mv where λ is the wavelength (m), h is the Planck constant (6.63 × 10-34 J s), p is the momentum of the particle (kg m s-1), m is its mass (kg) and v is its speed (m s-1).The wavelength is inversely proportional to the momentum: a faster or heavier particle has a shorter wavelength.Worked example 1Calculate the de Broglie wavelength of an electron (m = 9.11 × 10-31 kg) travelling at 2.0 × 106 m s-1.p = mv = 9.11 × 10-31 × 2.0 × 106 = 1.82 × 10-24 kg m s-1λ = h / p = 6.63 × 10-34 ÷ 1.82 × 10-24 = 3.6 × 10-10 mWorked example 2A 0.050 kg ball is thrown at 20 m s-1. Its momentum is 0.050 × 20 = 1.0 kg m s-1, so λ = 6.63 × 10-34 m. This is far smaller than any gap the ball could pass through, so everyday objects never show noticeable diffraction.If an electron has been accelerated from rest through a potential difference V, its kinetic energy is eV, and its momentum can then be found from Ek = p2 / 2m.
DeBroglie Wavelength
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Specification: Edexcel Physics (8PH0), AS-level, Topic 5: Waves and Particle Nature of Light. Topic: Quantum Physics.
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