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Trends in First Ionisation Energies Down a Group

OCR AS-level ChemistryPeriodicityLesson 6 of 14

The first ionisation energy decreases down a group. Although the nuclear charge increases, its effect is outweighed by the increased radius and to a lesser extent the increased shielding. So the nuclear attraction for the outer electron decreases as you go down the group.

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Key terms in this lesson

Ionisation
The loss or gain of electrons by an atom or molecule to form a charged ion.
First ionisation energy
The energy needed to remove one electron from each atom of one mole of atoms in their gaseous state to form one mole of gaseous +1 ions, under standard conditions.
Shielding
The repulsion of the electron to be removed by the electrons in the inner shells, which reduces nuclear attraction.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.

More in Periodicity

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