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Beryllium and Boron

Although there is a general trend in first ionisation energies across a period, and the ionisation energy increases across the period, except from group 2 to group 3.
Boron has a lower ionisation energy than beryllium because outer electron of beryllium is in the 2s sub-shell whilst the outer electron of Boron is in the 2p sub-shell.
The 2p electron is easier to remove than the 2s electron because the 2p sub-shell has a higher energy than the 2s sub-shell.
Period 2 ionisation energies kJmol-1:
LiBeBCNOFNe
520.2899.5800.61086.51402.31313.91681.02080.7

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Specification: OCR Chemistry A (H032), AS-level, 3.1.1 Periodicity. Topic: Periodicity.

Key terms in this lesson

Ionisation
The loss or gain of electrons by an atom or molecule to form a charged ion.
Electron shell
A main energy level occupied by electrons, given a principal quantum number n, with n = 1 closest to and lowest in energy relative to the nucleus.
Sub-shell
A subdivision of a main energy level (s, p, d or f) made up of orbitals of similar energy.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

More in Periodicity

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