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Trends in First Ionisation Energies Across a Period

There is a general increase in ionisation energy across a period.There is a sharp decrease from the end of one period to the beginning of the next.The atom radius decreases across a period as the number of protons (nuclear charge) increases. There is similar shielding as the outer electrons are in the same quantum shell but the increase in nuclear charge leads to a greater nuclear attraction so more energy is required to remove the electron.Period 2 ionisation energies kJmol-1:
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Specification: OCR Chemistry A (H032), AS-level, 3.1.1 Periodicity. Topic: Periodicity.

Key terms in this lesson

Ionisation
The loss or gain of electrons by an atom or molecule to form a charged ion.
Electron shell
A main energy level occupied by electrons, given a principal quantum number n, with n = 1 closest to and lowest in energy relative to the nucleus.
Shielding
The repulsion of the electron to be removed by the electrons in the inner shells, which reduces nuclear attraction.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

More in Periodicity

All 14 lessons in Periodicity · All OCR AS-level Chemistry topics