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Periodic Trends in Melting Points

Across periods 2 and 3, the melting point increases from groups 1 to 14 (4) then there is a sharp decrease in melting point between group 4 and 5. The melting point of groups 5 to group 8 are lower than those in the first four groups.The elements in groups 1 to 4 have giant structures. The elements in groups 5 to 7 have simple molecular structures and group 8 elements exist as single atoms.Giant structures are held together by strong metallic, covalent or ionic bonds and need a lot of energy to break these bonds. Simple molecules have weak intermolecular bonds between them. Less energy is needed to overcome these forces so they have much lower melting points.Period 2 Melting Points (K):
LiBeBCNOFNe
454156023483823635453.524.5

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Specification: OCR Chemistry A (H032), AS-level, 3.1.1 Periodicity. Topic: Periodicity.

Key terms in this lesson

Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.
Period
A horizontal row of the periodic table, containing elements with the same number of electron shells.

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