Skip to content

Distillation

Distillation separates a liquid from a mixture by boiling it and condensing the vapour. In organic synthesis it is used to remove a volatile product from a reaction mixture, or to separate liquids with different boiling points.The mixture is heated in a round-bottomed flask containing anti-bumping granules, which give smooth boiling. A still head holds a thermometer with its bulb level with the side arm, so it reads the temperature of the vapour leaving the flask. The vapour passes into a Liebig condenser, cooled by water that enters at the bottom and leaves at the top so the jacket stays full of cold water. The condensed liquid, the distillate, drips into a collecting flask.
Unlike reflux apparatus, the vapour does not return to the flask: once it has condensed it is collected. The apparatus must never be sealed, or pressure would build up. Organic liquids are flammable, so an electric heater or water bath is used rather than a Bunsen flame.Example: oxidising propan-1-ol with acidified potassium dichromate(VI) can give propanal (boiling point 49 °C) or propanoic acid. To obtain the aldehyde, the mixture is heated in distillation apparatus so that propanal distils off as soon as it forms, before it can be oxidised further. Propan-1-ol (97 °C) and propanoic acid (141 °C) have higher boiling points and stay in the flask.

Read the text

Read the text and highlight anything you think is important. When you go on, the text is hidden and you answer from memory.