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The Molecular Ion Peak

In the mass spectrum of a molecule, look for the main peak with the largest m/z value (ignoring the small M+1 peak caused by carbon-13). This is called the molecular ion peak and is the result of the whole molecule losing a single electron on collision with electrons.For example butane: C4H10 + e- → C4H10+ + 2 e-This will occur at m/z value = 58 which is the RMM value of butane.

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