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Mass Spectrum Example 4

Edexcel AS-level ChemistryMass SpectrometryLesson 8 of 9

Example 4: chloroethane, CH3CH2Cl

Chlorine has two isotopes, chlorine-35 and chlorine-37, which occur in the ratio of about 3:1. Any ion that contains one chlorine atom therefore appears as a pair of peaks 2 units apart, with heights in the ratio 3:1.

Diagram

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Key terms in this lesson

molecular ion
The positive ion formed when a whole molecule loses an electron in a mass spectrometer, giving a peak at the molecule's relative molecular mass.

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