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Mass Spectrum Example 1

Edexcel AS-level ChemistryMass SpectrometryLesson 5 of 9

Example 1: ethanol, CH3CH2OH (Mr = 46)

Diagram

To interpret a mass spectrum, first find the molecular ion peak, then work out what each fragment peak has lost from the molecular ion.

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Key terms in this lesson

base peak
The tallest peak in a mass spectrum, corresponding to the most abundant, most stable fragment ion.
molecular ion
The positive ion formed when a whole molecule loses an electron in a mass spectrometer, giving a peak at the molecule's relative molecular mass.

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