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Graphite

In graphite, each carbon atom forms three sigma bonds to 3 other carbon atoms forming interlocking hexagonal rings with bond angles 120°. The fourth electron is in a p orbital and p orbitals of adjacent carbon atoms are close enough to overlap and produce a cloud of delocalised electrons above and below the plane of the rings. Graphite is a solid lubricant as the layers can slide over each other easily and there are weak London forces between the layers. The lubricating properties are also helped by adsorbed gases on the surface of the carbon atoms.Graphene is a single layer of graphite.
Graphite is a giant covalent structure. It is made of hexagonally arranged carbon atoms covalently bonded together. Each carbon atom uses three of the outer electrons to form three covalent bonds with three other carbon atoms.The layers are held together by weak London forces.The spare electron is delocalised within each layer, above and below the plane of the rings. The delocalised electrons can move along the layers, so graphite is an electrical conductor.

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Specification: Edexcel Chemistry (8CH0), AS-level, Topic 2B: Structure. Topic: Discrete Molecules.

Key terms in this lesson

giant covalent lattice
A structure in which atoms are joined to several neighbours by strong covalent bonds extending throughout the whole solid.
delocalised electrons
Electrons that are free to move throughout a structure rather than being fixed between two particular atoms.

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