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Trends in Ionic Radii

There are large uncertainties in the measurement of ionic radii.Ionic radius depends on the nature of the ions and the co-ordination number.As you go down the group the ions have more electron shells therefore the ions get larger.Across a period, for ions with the same number of electrons (such as Na+, Mg2+ and Al3+), the ionic radius decreases as the number of protons increases. The electrons are attracted more strongly and pulled closer to the nucleus. The negative ions (P3-, S2-, Cl-) have an extra shell, so they are much larger.Period 3:
group 1 group 2 group 3
Na+Mg2+Al3+
protons1112 13
electrons 1010 10

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