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Addition Polymerisation

Edexcel AS-level ChemistryAlkenesLesson 13 of 19

Addition polymerisation joins many small alkene molecules, called monomers, into one very long chain molecule, a polymer. In each monomer the C=C double bond opens (the π bond breaks) and the carbon atoms form new single bonds to neighbouring monomers.

n CH2=CH2 → -[CH2-CH2]-n

Here n, the number of monomers joined, is very large (often thousands). The polymer is named by putting the monomer name in brackets after 'poly': ethene gives poly(ethene).

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Key terms in this lesson

atom economy
The percentage of the total mass of reactants that ends up as the desired product in a reaction.

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