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Addition of Hydrogen Halides

Edexcel AS-level ChemistryAlkenesLesson 7 of 19

Alkenes react with the hydrogen halides HCl, HBr and HI at room temperature. The H atom adds to one carbon of the C=C and the halogen atom adds to the other, giving a halogenoalkane.

CH2=CH2 + HBr → CH3CH2Br

The product here is bromoethane. The hydrogen halide is used as a gas, or as a concentrated solution. Cyclohexene reacts with HCl in the same way to give chlorocyclohexane.

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