A nucleophile is an electron pair donor. It has a lone pair of electrons that it can use to form a new covalent bond with an electron-deficient atom.The name means nucleus loving. Nucleophiles are attracted to positive centres, such as the δ+ carbon atom in the polar carbon-halogen bond of a halogenoalkane.Nucleophiles can be negative ions or neutral molecules. The three nucleophiles you need to know for halogenoalkanes are the hydroxide ion OH-, the cyanide ion CN- and the ammonia molecule NH3.Ammonia has no overall charge but can still act as a nucleophile because the nitrogen atom has a lone pair. Water can also act as a weak nucleophile using a lone pair on its oxygen atom.
Nucleophiles
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Specification: AQA Chemistry (7404), AS-level, 3.3.3.1 Nucleophilic substitution. Topic: Halogenoalkanes.
More in Halogenoalkanes
- Naming Halogenoalkanes
- Bond Polarity
- Physical Properties
- Reactivity of the Carbon-Halogen Bond
- Nucleophilic Substitution
- Reaction with Aqueous Sodium Hydroxide
- Reaction with Cyanide Ions
- Reaction with Ammonia
All 16 lessons in Halogenoalkanes · All AQA AS-level Chemistry topics