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Reaction with Aqueous Sodium Hydroxide

AQA AS-level ChemistryHalogenoalkanesLesson 8 of 16

Halogenoalkanes react with warm aqueous sodium hydroxide to form alcohols. This is a nucleophilic substitution in which the hydroxide ion is the nucleophile. It is also called hydrolysis.

For example: CH3CH2Br + NaOH → CH3CH2OH + NaBr. The ionic equation is CH3CH2Br + OH- → CH3CH2OH + Br-.

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