Skip to content

Neutralisation Reactions

Neutralisation reactions occur when an acid reacts with a base to form a salt and water.For example, hydrochloric acid reacts with sodium hydroxide to give sodium chloride and water. The equation for the reaction is:HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)The reaction is exothermic. The standard enthalpy change of neutralisation ΔneutHθ is the energy change that accompanies the reaction of an acid with a base to form one mole of water H2O (l) under standard conditions, all reactants and products being in their standard states.When carrying out the enthalpy change of a reaction between two aqueous solutions, the immediate surrounding is the solution itself, so a thermometer can be placed in the solution to record the temperature change.To correct for heat loss a cooling curve can be used. The temperature is measured every 30s until it stays constant. The reactants are mixed and the temperature is taken every 30s until the temperature has fallen for several minutes, A temperature time graph is plotted. To find the correct temperature, you can extrapolate back to the time when the reactants were mixed.

Read the text

Read the text and highlight anything you think is important. When you go on, the text is hidden and you answer from memory.

Specification: AQA Chemistry (7404), AS-level, 3.1.4.1 Enthalpy change. Topic: Energetics.

Key terms in this lesson

Mole
The amount of substance that contains as many particles as there are atoms in exactly 12g of carbon-12.
Enthalpy
A measure of the heat energy stored in a chemical system.
Enthalpy change
The heat energy transferred between the system and its surroundings during a process carried out at constant pressure.
Exothermic
Describes a reaction in which energy is transferred from the system to the surroundings, so the enthalpy change is negative.
Standard conditions
A pressure of 100 kPa, a temperature of 298 K, and, for solutions, a concentration of 1 moldm-3.

More in Energetics

All 24 lessons in Energetics · All AQA AS-level Chemistry topics