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Formation of Coloured Ions

Edexcel A-level ChemistryTransition MetalsLesson 6 of 21

Transition elements with incomplete d subshells have electrons that are initially in the ground state occupying lower energy levels. Usually all five d orbitals have the same energy level. In the presence of a ligand the energy levels split into two higher and three lower or two lower and three higher depending on the shape of the complex. When an electron absorbs a photon of visible light an electron in the lower energy level can be excited and occupy a higher energy orbital.

Diagram

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