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Rf Values

AQA A-level ChemistryChromatographyLesson 3 of 7

In TLC, each component moves a characteristic distance relative to the solvent. This is measured by its Rf value:

Rf = distance moved by the spot ÷ distance moved by the solvent front

Both distances are measured from the baseline, and the spot distance is measured to the centre of the spot. A spot can never move further than the solvent, so Rf is always between 0 and 1. It has no units.

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