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Reactions of Group 2 Oxides

Group 2 oxides react with water and release hydroxide ions to form alkaline solutions.CaO(s) + H2O(l) → Ca(OH)2(aq)Group 2 hydroxides are only slightly soluble in water so form a solid precipitate when the solution becomes saturated.For any Group 2 oxide MO the equation is:
MO(s) + H2O(l) → M(OH)2(aq)
The oxide ion reacts with water to release hydroxide ions:
O2- + H2O → 2OH-
Because they form alkalis, Group 2 oxides are basic oxides. The resulting solutions are colourless.The solubility of the Group 2 hydroxides increases down the group. Magnesium hydroxide is only slightly soluble in water, so few OH- ions are released and the solution has a pH of about 10. Barium hydroxide is much more soluble, so more OH- ions are released and the pH is about 13. The pH of these alkaline solutions therefore increases down the group, from about 10 to about 13.This basic nature is useful: farmers spread calcium hydroxide on fields to raise the pH of acidic soils.

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Specification: OCR Chemistry A (H032), AS-level, 3.1.2 Group 2. Topic: Reactivity Trends.

Key terms in this lesson

Ion
A positively or negatively charged atom or group of atoms, formed by the loss or gain of electrons.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.

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