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Group 2 Redox Reactions with Oxygen

Group 2 metals all react with oxygen to form metal oxides. The M2+ ions form ionic bonds with O2-ions.Magnesium burns with a brilliant white light to form magnesium oxide.
2Mg(s) + O2(g) → 2MgO(s)
This is a redox reaction. Each metal atom loses two electrons and is oxidised, and each oxygen atom gains two electrons and is reduced. The balanced equation is:
2Mg(s) + O2(g) → 2MgO(s)
The oxidation state of magnesium increases from 0 to +2 and the oxidation state of oxygen decreases from 0 to -2. The Group 2 metal acts as a reducing agent. For any Group 2 metal M:
2M(s) + O2(g) → 2MO(s)
The reactions are exothermic and give out energy to the surroundings. The electrostatic attraction between the M2+ ion and the O2- ion is an ionic bond, so the oxides exist as giant ionic lattices. They are all white solids with high melting points.Reactivity with oxygen increases down the group, because the outer electrons are further from the nucleus and more shielded, so they are lost more easily.

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Specification: OCR Chemistry A (H032), AS-level, 3.1.2 Group 2. Topic: Reactivity Trends.

Key terms in this lesson

Ion
A positively or negatively charged atom or group of atoms, formed by the loss or gain of electrons.
Group
A vertical column of the periodic table, containing elements with the same number of outer-shell electrons.

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