Pauli Exclusion Principle and Hund's RuleThe Pauli exclusion principle states that two electrons may occupy the same orbital only if they have opposite spins.Hund's rule states that electrons occupy orbitals of the same energy singly before pairing.The 4s orbital has a lower energy than the 3d orbitals, so the 4s orbital is filled before the 3d orbitals.The lowest energy orbitals are filled first.Each orbital can accommodate two electrons.
The exact energy of the electron is determined by the number of protons and the repulsion of the inner shell electrons so there are exceptions to the general rule.potassium1s2 2s2 2p6 3s2 3p64s1chromium1s2 2s2 2p6 3s2 3p6 4s1 3d5copper1s2 2s2 2p6 3s2 3p6 4s1 3d10
Predicting Electronic Configuration
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Specification: Edexcel Chemistry (8CH0), AS-level, Topic 1: Atomic Structure and the Periodic Table. Topic: Atomic Structure.
Key terms in this lesson
- orbital
- A region around a nucleus that can hold up to two electrons of opposite spin.
More in Atomic Structure
- Relative Molecular Mass from a Mass Spectrometer
- Quantum Shells
- Orbitals
- Electronic Configurations
- Energy Levels and Emission Spectra
- First Ionisation Energy
- Successive Ionisation Energies
- The Energy of an Electron
All 19 lessons in Atomic Structure · All Edexcel AS-level Chemistry topics