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Bonding in Alkenes

Edexcel AS-level ChemistryAlkenesLesson 2 of 19

The C=C double bond in an alkene is made of two different kinds of covalent bond: one σ (sigma) bond and one π (pi) bond.

A σ bond forms by the end-on (direct) overlap of orbitals, so its electron density lies directly between the two carbon nuclei. Every single covalent bond is a σ bond.

A π bond forms by the sideways overlap of two p orbitals, one on each carbon atom. Its electron density sits in two regions, one above and one below the plane of the molecule.

Diagram

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Key terms in this lesson

mean bond enthalpy
The average energy needed to break one mole of a particular covalent bond, measured over a range of compounds, with all species gaseous.

More in Alkenes

All 19 lessons in Alkenes · All Edexcel AS-level Chemistry topics