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Biodegradable Polymers

Edexcel AS-level ChemistryAlkenesLesson 19 of 19

A biodegradable polymer is one that can be broken down by microorganisms (bacteria and fungi) into simple substances such as carbon dioxide and water.

Most addition polymers are not biodegradable because their chains contain only strong, non-polar C-C and C-H bonds. Biodegradable polymers instead contain polar bonds in the chain, such as ester links, which can be hydrolysed by water and enzymes.

Examples:
• poly(lactic acid), PLA, made from lactic acid obtained from corn starch; used for food packaging, cups and disposable cutlery
• starch-based plastics, used for carrier bags and packing materials

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Key terms in this lesson

ester
An organic compound containing the -COO- group, formed for example from an alcohol and a carboxylic acid.
hydrolysis
The breaking of a chemical bond by reaction with water.

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