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Redox Reactions in Aqueous Solutions

Some species in aqueous solutions are neither oxidised or reduced. These include water molecules H2O and hydrogen ions H+ in acidic solutions and hydroxide ions OH- in alkaline solutions. They should be balanced separately.For example:unbalanced MnO4- in acidic solution where MnO4- is reduced to Mn2+
MnO4- + H+→ Mn2+
Balance the oxygens.
MnO4- + H+→ Mn2+ + 4H2O
Balance the hydrogens.
MnO4- + 8H+→ Mn2+ + 4H2O
Balance the charges with electrons.
MnO4- + 8H+ + 5e-→ Mn2+ + 4H2O
The Mn has been reduced from oxidation state of +7 to +2 so 5 electrons are needed.

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Specification: AQA Chemistry (7404), AS-level, 3.1.7 Oxidation, reduction and redox equations. Topic: Oxidation and Reduction.

Key terms in this lesson

Oxidation
The addition of oxygen, the removal of hydrogen, the loss of electrons, or an increase in oxidation number.
Oxidation number
A number that represents the number of electrons an atom has lost or gained, or would do if the compound were fully ionic.

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