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Ionic Half Equations

Oxidation is the loss of electrons. Reduction is the gain of electrons. Redox equations can be separated into two half equations that show the gain and loss of electrons.The reaction:Cu(s) + ½O2(g) → CuO(s)can be written as two half equations:Cu(s) → Cu 2+(s) +2e-½O2(g) +2e- → O 2-(s)
Metals react with acids to form salts and hydrogen gas.Magnesium reacts with hydrochloric acid to form magnesium chloride and hydrogen gas.
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
becomes:Mg(s) + 2H+(aq) → Mg2+(aq) + H2(g)The Chloride ions are not shown because they go from Cl-(aq) to Cl-(aq) and do not change in the reaction. As a result they are called spectator ions.The half equations for the reaction are:Mg(s) → Mg2+(aq) + 2e- and 2H+(aq) + 2e- → H2(g)

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Specification: AQA Chemistry (7404), AS-level, 3.1.7 Oxidation, reduction and redox equations. Topic: Oxidation and Reduction.

Key terms in this lesson

Spectator ion
An ion that is present in a reaction mixture but takes no part in the reaction, remaining unchanged.
Oxidation
The addition of oxygen, the removal of hydrogen, the loss of electrons, or an increase in oxidation number.
Reduction
The removal of oxygen, the addition of hydrogen, the gain of electrons, or a decrease in oxidation number.

More in Oxidation and Reduction

All 15 lessons in Oxidation and Reduction · All AQA AS-level Chemistry topics