For a chemical reaction to occur, the bonds within the reactants must be broken and new bonds must be formed between the atoms to make the products.The energy required to break the bonds is called the Activation energy Ea. It is the minimum energy required for the reaction to take place.Reactions with low activation energies take place rapidly because the energy needed to break the bonds is readily available from the surroundings.Reactions with very high activation energies will take place very slowly or not at all because the activation energy acts as an energy barrier to the reaction.The Maxwell-Boltzmann distribution shows the spread of energies of the molecules in a gas at a given temperature. Only the molecules with energy equal to or greater than Ea, shown by the area under the curve to the right of Ea, have enough energy to react.

Maxwell-Boltzmann Distribution and Activation Energy
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Specification: AQA Chemistry (7404), AS-level, 3.1.5.2 Maxwell-Boltzmann distribution. Topic: Kinetics.
Key terms in this lesson
- Exothermic
- Describes a reaction in which energy is transferred from the system to the surroundings, so the enthalpy change is negative.
- Activation energy
- The minimum energy required for a reaction to take place.
More in Kinetics
- Activation Energy
- Exothermic Reactions
- Endothermic Reactions
- Maxwell-Boltzmann Distribution
- The Effect of Temperature on Reaction Rate
- Catalysts
- Catalytic Converters
- Exam Style Question - 1
All 14 lessons in Kinetics · All AQA AS-level Chemistry topics