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Low Resolution Mass Spectrometry

Low resolution mass spectrometryshows the m/z ratio or mass-to-charge ratio of each isotope and the corresponding percentage abundances.Different isotopes are detected separately because they have different masses.The relative heights of the peak gives the relative abundances and the m/z ratio of a single charged ion gives the relative mass of the isotope.High resolution mass spectrometry can measure mass accurately to 5d.p. e.g. an atom of 12C has a mass of 12.00000 atomic mass units and an atom of 16O has a mass of 15.9949u.Low resolution mass spectrometry gives the m/z to the nearest whole number and may not be enough to distinguish between two molecules having the same molecular mass to the nearest whole number.

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Specification: AQA Chemistry (7404), AS-level, 3.1.1.2 Mass number and isotopes. Topic: Atomic Structure.

Key terms in this lesson

Isotopes
Atoms of the same element with the same number of protons but different numbers of neutrons.
Mass spectrometer
An instrument used to measure the percentage abundances of isotopes in a sample of an element, from which relative atomic mass can be calculated.

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