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Structural Isomers

Structural isomers of alkanes have the same molecular formula but different arrangements of the carbon chain. For alkanes these are chain isomers.Methane, ethane and propane have no isomers. Butane, C4H10, has two: butane and 2-methylpropane.Pentane, C5H12, has three: pentane, 2-methylbutane and 2,2-dimethylpropane. Hexane, C6H14, has five.The number of possible isomers increases very quickly as the number of carbons increases. There are 75 isomers of C10H22.When drawing isomers, check each one by naming it. Two drawings that give the same name are the same molecule, often just drawn bent or numbered from the other end.

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