Transition metal 2+ ions form octahedral hexaaqua II complexes with water. Transition metal 3+ ions form hexaaqua 3+ ions in water. In both cases water forms six co-ordinate bonds with the central metal ion. Hexaaqua complexes are slightly acidic in water due to their dissociation of water molecules to release H+ ions.Due to the increased charge density of the Fe3+ ion, it is able to polarise the water molecule more thus dissociating it more easily. Transition metal 3+ ions form more acidic solutions than 2+ ions. They are smaller and have a higher charge therefore are more polarising.Further hydrolysis occurs until a precipitate is formed.
Hydration of Metal Ions
Read the text
Read the text and highlight anything you think is important. When you go on, the text is hidden and you answer from memory.
Specification: OCR Chemistry A (H432), A-level, 5.3.1 Transition elements. Topic: Transition Metals.
Key terms in this lesson
- co-ordinate bond
- A covalent bond in which both shared electrons are supplied by one of the two bonding atoms. Also called a dative covalent bond.
More in Transition Metals
- Redox Titrations
- Heterogeneous Catalysts
- Homogeneous Catalysts
- Autocatalysis
- Reaction with Ammonia Solution
- Reaction with Sodium Hydroxide
- Reaction with Sodium Carbonate
- Test for Transition Metal Ions
All 21 lessons in Transition Metals · All OCR A-level Chemistry topics