In organic chemistry, reduction is the addition of hydrogen or the removal of oxygen. In equations the reducing agent is shown as [H].Aldehydes are reduced to primary alcohols and ketones to secondary alcohols using NaBH4, for example CH3CHO + 2[H] → CH3CH2OH.The hydride ion H- from NaBH4 acts as a nucleophile and attacks the δ+ carbon of the C=O group. This is nucleophilic addition.Reduction is the reverse of the oxidation of alcohols. Alkenes are reduced to alkanes by hydrogen with a nickel catalyst, and nitrobenzene is reduced to phenylamine by tin and concentrated HCl.
Reduction
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Specification: OCR Chemistry A (H432), A-level. Topic: Reactions and Reactive Species.
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